Teaching, Training and Publishing Platform for Everyone

Teaching, Training and Publishing Platform for Everyone

Effects of Vegetable Seed Oils Concentration in Bio-Demulsifiers on Demulsification of Nigerian Crude Oil

Deborah Chidinma Nwakuba1,2 Ibrahim Ali Mohammed-Dabo2 and Haruna Ibrahim3

1National Research Institute for Chemical Technology (NARICT), Zaria-Nigeria
2Chemical Engineering Department, Ahmadu Bell University, Zaria-Nigeria
3Kaduna Polytechnic, Kaduna-Nigeria

Vol 4 (3&4), pp. 7-19, October 2023
https://doi.org/10.47721/ARJB20230403015

Copyright © 2023 Author(s) and Skies Educational
This article is published under the terms of the Creative Commons Attribution License 4.0
Received: 29th June 2023          Accepted: 24th July 2023            Published: 31st October 2023

AbstractDownload PDFReferencesAuthorsArticle MetricsHow to Cite

Abstract

In search of environmentally friendly petroleum processing, three bio-demulsifiers were synthesized from Nigerian vegetable seed oils. The synthesized vegetable seed oils were Mahogany, Neem, and Calabash. Their oils were mechanically extracted and mixed with liquid detergent, camphor, starch, and paraffin wax to form bio-demulsifiers. The green demulsifiers produced were mixed with synthetic crude oil in the ratios of 0.5:50, 1:50, 1.5:50, 2:50, and 2.5:50 volume/volume in mL. Studies on the effects of their concentration in the demulsification of water-in-oil emulsion were conducted. Mahogany demulsifier of formulation M8 1.5:50 and M8 2:50 (volume of demulsifier to the volume of synthetic crude) had 78% performance. This was followed by N8 1.5:50 which had 77% performance. The highest 70% water removal performance by calabash demulsifiers was recorded by C1 0.5:50, C1 2:50, and C1 2.5:50. The lowest performance was recorded by N1 1:50 and N1 1.5:50 which had a performance of 35% water removal. With these results, Mahogany seed oil can be conveniently used to prepare bio-demulsifiers to save our environment and production cost.

Keywords: Bio-demulsifiers, concentration, crude oil, demulsification, effects, Vegetable Seed Oils

Effects of Vegetable Seed Oils Concentration in Bio-Demulsifiers on
Demulsification of Nigerian Crude Oil

References

Adebanjo, F. O., & Aduroja, O. C. (2015). Development of Local Demulsifier for Water-In-Oil Emulsion Treatment. International Journal of Sciences: Basic and Applied Research (IJSBAR) Volume, 24, 301-320.

Arifin, T. S. T., Yahya, E., & Husin, H. (2016). The rheology of light crude oil and water-in-oil-emulsion. Procedia Engineering, 148, 1149-1155.

Bera, A., & Babadagli, T. (2017). Effect of native and injected nano-particles on the efficiency of heavy oil recovery by radiofrequency electromagnetic heating. Journal of Petroleum Science and Engineering, 153, 244-256.

Clark, J. P. (2013). Emulsions: when oil and water do mix. Food Technol, 67(8), 1-9.

Dardor, D., Al-Maas, M., Minier-Matar, J., Janson, A., Sharma, R., Hassan, M. K., … & Adham, S. (2021). Protocol for preparing synthetic solutions mimicking produced water from oil and gas operations. ACS omega, 6(10), 6881-6892.

Dhandhi, Y., Chaudhari, R. K., & Naiya, T. K. (2022). Development in the separation of oilfield emulsion toward green technology–A comprehensive review. Separation Science and Technology, 57(10), 1642-1668.

Flores-Andrade, E., Allende-Baltazar, Z., Sandoval-González, P. E., Jiménez-Fernández, M., Beristain, C. I., & Pascual-Pineda, L. A. (2021). Carotenoid nanoemulsions stabilized by natural emulsifiers: Whey protein, gum Arabic, and soy lecithin. Journal of Food Engineering, 290, 110208.

Francis A. O., Sulaiman A. D., and Abdulsalam S. (2016). Stability Study of Some Selected Nigerian Crude Oil Emulsions and the Effectiveness of Locally Produced Demulsifier. Journal of Energy Technologies and Policy ISSN 2224-3232 Vol.6, No.2, www.iiste.org

Francis, A. O., Sulaiman, A. D. I., & Abdulsalam, S. (2016). Stability Study of Some Selected Nigerian Crude Oil Emulsions and the Effectiveness of Locally Produced Demulsifier. J Energy Technol Policy, 6(2), 48-59.

Gómez-Jaimes, F. N., Blanco-Tirado, C., & Combariza, M. Y. (2020). Amidated cellulose nanofibrils as demulsifying agents for a natural water-in-heavy-crude-oil emulsion. Energy & Fuels, 34(11), 14012-14022.

Han, L., Lu, K., Zhou, S., Qi, B., & Li, Y. (2022). Co-delivery of insulin and quercetin in W/O/W double emulsions stabilized by different hydrophilic emulsifiers. Food Chemistry, 369, 130918.

Huang, W., Zhu, D., Fan, Y., Xue, X., Yang, H., Jiang, L., … & Komarneni, S. (2020). Preparation of stable inverse emulsions of hydroxyethyl methacrylate and their stability evaluation by a centrifugal coefficient. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 604, 125309.

Husain, A., & Al-Harthi, M. A. (2022). Chemical treatment of oilfield wastewater and the effect of temperature on treatment efficiency: A review. Journal of Petroleum Science and Engineering, 111089.

Koubaa, M., Mhemdi, H., & Vorobiev, E. (2016). Influence of canola seed dehulling on the oil recovery by cold pressing and supercritical CO2 extraction. Journal of Food Engineering, 182, 18-25.

Rajeev, P., Surendranathan, A. O., & Murthy, C. S. (2012). Corrosion mitigation of the oil well steels using organic inhibitors–a review. J. Mater. Environ. Sci, 3(5), 856-869.

Raji, R. O. (2021). Development of Biosurfactants-iron Oxide Nanoparticles-Biochar Formulation for Remediation of Crude Oil Contaminated Soil (Doctoral dissertation).

Rostami, P., Mehraban, M. F., Sharifi, M., Dejam, M., & Ayatollahi, S. (2019). Effect of water salinity on oil/brine interfacial behaviour during low salinity waterflooding: A mechanistic study. Petroleum, 5(4), 367-374.

Saad, M. A., Kamil, M., Abdurahman, N. H., Yunus, R. M., & Awad, O. I. (2019). An overview of recent advances in state-of-the-art techniques in the demulsification of crude oil emulsions. Processes, 7(7), 470.

Severino, P., Pinho, S. C., Souto, E. B., & Santana, M. H. (2011). Polymorphism, crystallinity and hydrophilic–lipophilic balance of stearic acid and stearic acid–capric/caprylic triglyceride matrices for production of stable nanoparticles. Colloids and Surfaces B: Biointerfaces, 86(1), 125-130.

Shehzad, F., Hussein, I. A., Kamal, M. S., Ahmad, W., Sultan, A. S., & Nasser, M. S. (2018). Polymeric surfactants and emerging alternatives used in the demulsification of produced water: A review. Polymer Reviews, 58(1), 63-101.

Souas, F., Safri, A., & Benmounah, A. (2021). A review on the rheology of heavy crude oil for pipeline transportation. Petroleum Research, 6(2), 116-136.

Sousa, A. M., Pereira, M. J., & Matos, H. A. (2022). Oil-in-water and water-in-oil emulsions formation and demulsification. Journal of Petroleum Science and Engineering, 210, 110041.

Sulaiman, A. D., Abdulsalam, S., & Francis, A. O. (2015, August). Formulation of demulsifiers from locally sourced raw materials for treatment of a typical Nigerian crude oil emulsion. In SPE Nigeria Annual International Conference and Exhibition. OnePetro.

Umar, A. A., Saaid, I. B. M., Sulaimon, A. A., & Pilus, R. B. M. (2018). A review of petroleum emulsions and recent progress on water-in-crude oil emulsions stabilized by natural surfactants and solids. Journal of Petroleum Science and Engineering, 165, 673-690.

Ye, F., Zhang, Z., Ao, Y., Li, B., Chen, L., Shen, L., … & Mi, Y. (2022). Demulsification of water-in-crude oil emulsion driven by a carbonaceous demulsifier from natural rice husks. Chemosphere, 288, 132656.

Yonguep, E., Fabrice, K. K., Katende, J. K., & Chowdhury, M. (2022). The formation, stabilization and chemical demulsification of crude oil-in-water emulsions: A review. Petroleum Research.

Yonguep, E., Fabrice, K. K., Katende, J. K., & Chowdhury, M. (2022). The formation, stabilization and chemical demulsification of crude oil-in-water emulsions: A review. Petroleum Research.

Zheng, S., & Yang, D. (2017). Determination of individual diffusion coefficients of C3H8/n-C4H10/CO2/heavy-oil systems at high pressures and elevated temperatures by dynamic volume analysis. SPE Journal, 22(03), 799-816.

Authors

Deborah Chidinma Nwakuba is a researcher at National Research Institute for Chemical Technology (NARICT), Zaria-Nigeria and Chemical Engineering Department, Ahmadu Bell University, Zaria-Nigeria

Ibrahim Ali Mohammed-Dabo is a researcher at Chemical Engineering Department, Ahmadu Bell University, Zaria-Nigeria

Haruna Ibrahim is a researcher at Kaduna Polytechnic, Kaduna-Nigeria

Article Metrics

Google Scholar Metrics

How to Cite

Deborah C. N, Mohammed-Dabo I.A and Haruna I (2023): Effects of vegetable seed oils concentration in bio-demulsifiers on demulsification of Nigerian crude oil. Appl. Res. J. Biotechnol. https://doi.org/10.47721/ARJB20230403015

Leave a Comment

Your email address will not be published. Required fields are marked *

Scroll to Top