Skies Educational

Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves

Haruna Ibrahim*1, Idris M. Bugaje2 and Patrick O. Nwosibe1
1Department of Chemical Engineering, Kaduna Polytechnic, Kaduna-Nigeria.
2National Board for Technical Education, Kaduna-Nigeria

*Correspondence to: [email protected] ; 08133106608
Vol 4(1&2), pp. 1-9, April, 2023
https://doi.org/10.47721/ARJST20230401029

Copyright © 2023 Author(s) and Skies Educational
This article is published under the terms of the Creative Commons Attribution License 4.0
Received: 23rd November 2022          Accepted: 28th March 2023            Published: 30th April 2023

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Abstract

This work was aimed at; investigating a clean method of removing waste leaves from the waste stream, converting them into fatty acids, biodiesel feedstock, or upgrading to deoxygenated fuels for higher energy content. Waste leaves of Gmelina arborea were collected, cleaned, and pulverized with ceramic mortar and pestle. A 50g of the pulverized leaves were thermally hydrolyzed over 0.75g of H2SO4, NaOH, and ZnCl2 catalysts and 500mL distilled water on a GallenKamp hot plate magnetic stirrer at 100oC for 30 minutes. The extracts were filtered with a sheet cloth, dried with 0.2% anhydrous MgSO4 and weighed. Each extract was analyzed with a gas chromatography and mass spectroscopy (GC-MS) machine to determine its components and compositions. The quantities of fatty acids extracted over H2SO4, NaOH, and ZnCl2 were 228.30g, 184.30g and 118.43g respectively. The biodiesel estimated from the fatty acids extracted was found to be 240.02g, 193.8g and 124.39g respectively. Also, the estimated bio-hydrogenated gasoline (BHG) and bio-hydrogenated diesel (BHD) were found to be 192.27g, 154.97g and 87.37g respectively. The process yields more biodiesel than conventional seed oils. This process would be more economical to achieve a biofuel economy than the use of lipids from oil seeds.

Keywords: biofuels, development, fatty acids, feedstocks, Gmelina arborea, waste leaves,

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Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves

References

Brenna, E., Colombo, D., Lecce, G.D., Gatti, F.G., Ghezzi, M.C. Tentori, F., Tessaro, D. and Viola, M. (2020). Conversion of Oleic Acid into Azelaic and Pelargonic Acid by a Chemo-Enzymatic Route. Molecules, 25, 1882; doi: 10.3390/molecules25081882

Edeh, I., Overton, T. and Bowra, S. (2019). Renewable diesel production by hydrothermal decarboxylation of fatty acids over platinum on carbon. Biofuels, DOI: 10.1080/17597269.2018.1560554 catalyst

Hu, W., Wang, H., Lin, H., Zheng, Y., Ng, S., Shi, M., Zhao, Y. and Xu, R. (2019). Catalytic Decomposition of Oleic acid to fuels and Chemicals: Roles of Catalyst Acidity and Basicity on the Product Distribution and Reaction Pathways. Catalysts MDPI, 9, 1063; doi: 10.3390/catal9121063.

Ibrahim H., Nwanya K.O., Ayilara S., Adegbola O., Nwakuba D.C., Tyoor A.D., Ba’are A.M, and Shuaibu H. (2015). The potential of Earleaf Acacia (Acacia Auriculiformis) leaves for Industrial Raw Materials. International Journal of Scientific Engineering and Applied Science (IJSEAS) Vol. 1, ISSN 2395-3470, pp 462-467. Available at: www.ijseas.com

Kochaputi, N., Kongmark, C., Khemthong, P., Butburee, T., Kuboon, S., Worayingyong, A. and Faungnawakij, K. (2019). Catalytic Behaviours of Supported Cu, Ni and CO phosphide Catalysts for Deoxygenation of Oleic Acid. Catalysts, MDPI, 9, 715; doi: 10.3390/catal9090715.

Omokanye, A.T., Lamidi, O.S. and Oyeleke, L.S. (2014). Gmelina Arborea at Shika, Nigeria: Nutritive Indices, Preference and Intake of Plant Parts by Yankasa Sheep. International Journal of Research in Agriculture and Forestry Volume 1, Issue 2, PP 31-36, ISSN 2394-5907.
Prota 4U (accessed 22/06/2022). Gmelina arborea Roxb. ex Sm. Available at: https://www.prota4u.org/database/protav8.asp?g

Sembiring, K.C., Aunillah, A., Minami, E. and Saka, S. (2018). Renewable gasoline production from oleic acid by oxidative cleavage followed by decarboxylation. Renewable Energy, 602-607

Wu, J., Shi, J., Fu, J., Leidl, J.A., Hou Z. and Lu, X. (2016). Catalytic Decarboxylation of Fatty Acids to Aviation Fuels over Nickel Supported on Activated Carbon. Scientific Reports | 6:27820 | DOI: 10.1038/srep27820

Authors

Haruna Ibrahim

He is a researcher / lecturer in the Department of Chemical Engineering, Kaduna Polytechnic, Kaduna-Nigeria.

Idris M. Bugaje

He is a researcher / lecturer in the National Board for Technical Education, Kaduna-Nigeria

Patrick O. Nwosibe

He is a researcher / lecturer in the Department of Chemical Engineering, Kaduna Polytechnic, Kaduna-Nigeria.

Article Metrics

Citing ‘Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves’

BibTexRISAPAHarvardIEEEMLAVancouverChicago
@article{Ibrahim_2023,
	doi = {10.47721/arjst20230401029},
	url = {https://doi.org/10.47721%2Farjst20230401029},
	year = 2023,
	month = {apr},
	publisher = {Skies Educational},
	volume = {4},
	number = {1},
	pages = {1--9},
	author = {Haruna Ibrahim and   and Idris Bugaje and Patrick Nwosibe and   and},
	title = {Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves},
	journal = {Applied Research Journal of Science and Technology}
}
TY  - JOUR
DO  - 10.47721/arjst20230401029
UR  - http://dx.doi.org/10.47721/arjst20230401029
TI  - Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves
T2  - Applied Research Journal of Science and Technology
AU  - Ibrahim, Haruna
AU  - 
AU  - Bugaje, Idris
AU  - Nwosibe, Patrick
AU  - 
AU  - 
PY  - 2023
DA  - 2023/04/30
PB  - Skies Educational
SP  - 1-9
IS  - 1
VL  - 4
SN  - 2695-1738
ER  - 

Feedback: [email protected]

Ibrahim, H., Bugaje, I., & Nwosibe, P. (2023). Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves. Applied Research Journal of Science and Technology, 4(1), 1–9. https://doi.org/10.47721/arjst20230401029

Feedback: [email protected]

[1]H. Ibrahim, I. Bugaje, and P. Nwosibe, “Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves,” Applied Research Journal of Science and Technology, vol. 4, no. 1, pp. 1–9, Apr. 2023, doi: 10.47721/arjst20230401029.

Feedback: [email protected]

Ibrahim, Haruna, et al. “Development of Fatty Acids as Feedstocks for Biofuels from Gmelina Arborea Waste Leaves.” Applied Research Journal of Science and Technology, vol. 4, no. 1, Apr. 2023, pp. 1–9. Crossref, https://doi.org/10.47721/arjst20230401029.

Feedback: [email protected]

1. Ibrahim H, Bugaje I, Nwosibe P. Development of fatty acids as feedstocks for biofuels from Gmelina arborea waste leaves. Applied Research Journal of Science and Technology [Internet]. 2023 Apr 30;4(1):1–9. Available from: http://dx.doi.org/10.47721/arjst20230401029

Feedback: [email protected]

Ibrahim, Haruna, Idris Bugaje, and Patrick Nwosibe. “Development of Fatty Acids as Feedstocks for Biofuels from Gmelina Arborea Waste Leaves.” Applied Research Journal of Science and Technology 4, no. 1 (April 30, 2023): 1–9. https://doi.org/10.47721/arjst20230401029.

Feedback: [email protected]

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